Remove user from DirSync (move to OU which is not synced, will only work when OU Filtering is used.So, how did I resolve this? See below: When there are duplicates: After this is set, DirSync should match the accounts correctly. You can only add this attribute to Office 365 accounts. When UPN/SMTP matching failed you can merge those accounts again by setting the ImmutableID on the Office 365 account (MsolUser) which is derived from the AD user’s ObjectGuid.
If not, it fails matching and you end up with either duplicate accounts (one cloud user and a DirSynced user with the same name/lastname/displayname) or get an InvalidSoftMatch. With the next sync it should match both accounts. But be sure to create the user with a full UPN matching the one in Office 365 and SMTP addresses that are present on the Cloud account. If there is already a cloud account and there is need for a synced account, you can create an AD account in DirSynced OU's. There were also accounts that failed to sync and thus failed to sync all attributes properly. For some reason (there were some cloud users created before DirSync was enabled) there were duplicate users, because DirSync failed to match the already present cloud user and the corresponding AD (Active Directory) user. Recently I had to fix some issues with DirSync.
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